As long as the miniPCIE card supports SATA port multipliers, you can run any RAID array you wish off it (with the help of an external enclosure such as my Lian Li EX-50).
The pictures of the Zotac you linked to show a free miniPCIe slot on the backside of the PCB. Physical SATA cable routing probably requires you to be 'creative' with the Zotac's enclosure.
As for hardware RAID0: never tried, but I would indeed think it works the way you proposed; and can easily be tested if you have disposal of a hardware RAID or fakeRAID controller.
The pictures of the Zotac you linked to show a free miniPCIe slot on the backside of the PCB. Physical SATA cable routing probably requires you to be 'creative' with the Zotac's enclosure.
As for hardware RAID0: never tried, but I would indeed think it works the way you proposed; and can easily be tested if you have disposal of a hardware RAID or fakeRAID controller.
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