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Major solar cell advance

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  • Major solar cell advance

    Seems the Berkley National Laboratory - Solar Energy Materials Research Group is closing in on a practical way to manufacture solar cells that convert a wide range of wavelengths into electricity, in this case from IR to UV. This could make for a helluva gain in efficiency.

    Berkeley Lab has long pioneered new materials and new methods for making solar cells that can convert the full spectrum of sunlight to electrical energy. Now Berkeley Lab researchers and their colleagues have demonstrated a new solar cell design that not only captures the sun’s full spectrum, it is also practical to make using common manufacturing techniques in the semiconductor industry.


    The Practical Full-Spectrum Solar Cell Comes Closer
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    Although full-spectrum solar cells have been made, none yet have been suitable for manufacture at a consumer-friendly price. Now Wladek Walukiewicz, who leads the Solar Energy Materials Research Group in the Materials Sciences Division (MSD) at the U.S. Department of Energy’s Lawrence Berkeley National Laboratory (Berkeley Lab), and his colleagues have demonstrated a solar cell that not only responds to virtually the entire solar spectrum, it can also readily be made using one of the semiconductor industry’s most common manufacturing techniques.

    The new design promises highly efficient solar cells that are practical to produce. The results are reported in a recent issue of Physical Review Letters, available online to subscribers.
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    The new solar cell material from Walukiewicz and Yu and their colleagues in Berkeley Lab’s MSD and RoseStreet Labs Energy, working with Sumika Electronics Materials in Phoenix, Arizona, is another multiband semiconductor made from a highly mismatched alloy. In this case the alloy is gallium arsenide nitride, similar in composition to one of the most familiar semiconductors, gallium arsenide. By replacing some of the arsenic atoms with nitrogen, a third, intermediate energy band is created. The good news is that the alloy can be made by metalorganic chemical vapor deposition (MOCVD), one of the most common methods of fabricating compound semiconductors.
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    The results of the test showed that light penetrating the blocked device efficiently yielded current from all three energy bands – valence to intermediate, intermediate to conduction, and valence to conduction – and responded strongly to all parts of the spectrum, from infrared with an energy of about 1.1 electron volts (1.1 eV), to over 3.2 eV, well into the ultraviolet.
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    With the new, multiband photovoltaic device based on gallium arsenide nitride, the research team has demonstrated a simple solar cell that responds to virtually the entire solar spectrum – and can readily be made using one of the semiconductor industry’s most common manufacturing techniques. The results promise highly efficient solar cells that are practical to produce.
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    Dr. Mordrid
    ----------------------------
    An elephant is a mouse built to government specifications.

    I carry a gun because I can't throw a rock 1,250 fps

  • #2
    Great news. What efficiency though? I imagine over 50-60%, which means more power and/or significantly smaller cells.
    FT.

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    • #3
      Originally posted by Fat Tone View Post
      Great news. What efficiency though? I imagine over 50-60%, which means more power and/or significantly smaller cells.
      I doubt it. The energy band of 1 decade today gives about 15%. Theoretically, all other things being equal, three bands will give 45% but somewhat less in practice, as there will be some absorption in the outer layers, possibly 40%. Then there is a problem of atmospheric absorption of the irradiance in the IR and UV. No problem in space, but the atmosphere becomes pretty opaque with some quite wide bandwidths with certain gases. Even so, in space, the sun, being a near-black body radiator, emits its radiation in the form of a gaussian curve, with the peak in the visible spectrum, dropping off on either side. On the earth's surface, this curve has bites taken out of it, because of the absorption.

      There is another important point: 6 sigma GaAs costs ~$100/g, the nitride being even more expensive. Even with thin film techniques, it ain't going to be given away, compared with silicon.

      I think that IF it is developed to production, it may be reserved for space apps.
      Brian (the devil incarnate)

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      • #4
        We'll see if Brian's speculations hold. Some GaAs cells already run close to 40% efficient. This could well drive that up more than just a few points, and GaAs is used in much thinner layers than silicon, a few microns vs. almost 100 microns.

        I also see that the U of Illinois has figured out how to grow 10 layers of GaAs thin films that can easily be separated later. That's called production efficiency, and it drives prices down.
        Dr. Mordrid
        ----------------------------
        An elephant is a mouse built to government specifications.

        I carry a gun because I can't throw a rock 1,250 fps

        Comment


        • #5
          Hypothesis OK, speculation, no! Spectra and physical laws of gaseous absorption are very well known and documented. And the GaAs devices in the 30-35% efficiency range already use the same technology and have done for several years. What is new here is the use of Ga(As-N) substrates.
          Brian (the devil incarnate)

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